Carlson, F B, Yardumian, L H, Atwood, M T. TOSCOAL process: coal liquefaction and char production. Paper No. 15e. [Application of oil shale retorting technology to coal processing; process description]. United States.
During coalification, the chemical structure gradually changes to an aromatized structure, acquiring more stability and compactness as the methyl carbons present in the aliphatic chain changes to aromatic carbons thus reducing the spacing between the aromatic units (Blayden et al. 1944; Hirsch 1954; Cartz and Hirsch 1960; Manoj and Kunjomana 201...
Conversion of raw coal to distillate liquid and gaseous hydrocarbon products by solvent liquefaction in the presence of molecular hydrogen employing recycle of mineral residue is commonly performed at a higher thermal efficiency than conversion of coal to pipeline gas in a gasification process employing partial oxidation and methanation reactions.
In this study, coal fly ash was functionalized, using a simple onestep process (loading with Al3+ and sulfonation), to yield a solid acid catalyst (S/AlCFA) with strong acid sites. The catalyst was then used to produce furfural from xylose in a biphasic system (H2O(NaCl)/tetrahydrofuran). The furfural yield reached 82% at 180 °C60 min with catalyst/xylose ratio of : (w/w). With the ...
CoProcessing refers to the combined processing of coal and petroleumderived heavy oil feedstocks. The coal feedstocks used are those typically utilized in direct coal liquefaction: bituminous, subbituminous, and lignites. Petroleumderived oil, is typically a petroleum residuum, containing at least 70 W% material boiling above 525{degrees}C.
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All direct coal liquefaction methods, such as HCoal, SolventRefined Coal, and Exxon Donor Solvent processes, are alike in one principal point: coal is thermally solubilized with certain solvents, usually coalderived, with or without catalysts. If heated in a proper liquid for a short time, most of the coal dissolves.
Abstract. Hydrocarbon Technologies (HTI) has been working on a feasibility study for the construction of a Direct Coal Liquefaction Plant in Shenhua coalfield of China. HTI's direct coal liquefaction process, consisting primarily of two backmixed reactor stages plus a fixedbed inline hydrotreater, operates at a pressure of 17 MPa and reactor ...
We have launched ISKG for indirect coal liquefaction process, its oriented applications are of great significance in optimizing HAZOP, strengthening industrial safety and popularizing safety prevention awareness. Section 2 is the related work, which mainly reviews HAZOP and KG. Section 3 is the method, we elaborate the development process of ...
The direct coal liquefaction process usually produces a liquefaction residue of about 30% of its coal feed. The effective utilization of the coal liquefaction residue (CLR), which contains about ...
catalysis liquid fuels lignin conversion Introduction Fuels are needed to power electricity and transportation, in the US and the rest of the world. Currently, the bulk of the power and transportation fuels rely on petroleum, coal and natural gas, with some contributions from hydroelectric, nuclear power, biomass and other alternatives.
the process to dissolve the coal and to transfer externally produced hydrogen to the coal molecules. Catalytic liquefaction resembles solvent extraction, except that hydrogen is added to the coal with the aid of a catalyst. Figure presents the flow diagram of a typical solvent extraction or catalytic liquefaction plant. These coal ...
The purpose of coal conversion is the production of alternative fuels, including motor fuels, or the generation of a range of chemicals from coal by process routes, such as gasification, direct and indirect liquefaction, hydropyrolysis, and plasmapyrolysis. The application of these techniques is essential if the large reserves of coal are to be ...
The coal hydrogenation reaction process is simply considered as three steps. In the first step, the smaller molecules associated with coal structure units are released as some gases and water in the condition of solvent and heating. In this step, some weaker bonds of the coal structure units are ruptured to form free radicals. The radicals are stabilized by hydrogen atoms from donor solvent ...
The occurrence of sulfur in coal direct liquefaction residue affects its further high quality and high value utilization. Electrochemical desulfurization is characterized by mild reaction conditions, simple operation, easy separation of sulfur conversion products and little influence on the properties of the liquefied residue. An anodic electrolytic oxidation desulphurization experiment was ...
Irdi et al. (1998) deashed and gasified DCLR to improve the economy of the direct coal liquefaction process. DCLR can be used as a raw material for preparing hydrogen for the coal liquefaction reaction process. It can be mixed and cogasified with raw coal at a high temperature . Preparation process. Mixing Process.
A process for twostage catalytic hydrogenation and liquefaction of coal to produce increased yields of lowboiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a processderived liquid solvent and fed at temperature below about
Abstract. First operated in 1973 to refine a sulfurfree solid fuel from coal, the Electric Power Research Institute's small pilot plant at Wilsonville, Alabama, is now a focal point for research and development in coal liquefaction. The solventrefined coal process (SRC) is largely free of ash and so low in sulfur content that it can be burned ...
Coal resources have been used to produce liquid transportation fuels by several process routes collectively referred to as coal liquefaction or, more generally stated, as coal to liquids (CTL). Early records of coal conversion to liquid fuel date to 1913 and an extraction process developed by Friedrich Bergius in Germany [ 7 ].
The growing demand for petroleum, accompanied by the declining petroleum reserves and the concerns over energy security, has intensified the interest in direct coal liquefaction (DCL), particularly in countries such as China which is rich in coal resources, but short of petroleum. In addition to a general introduction on the mechanisms and processes of DCL, this paper overviews some recent ...
Coal liquefaction is very powerful if you choose to make plastic onsite. With traditional oil processing, you need both oil and coal close to water, while liquefaction allows you to forget the oil and use only the coal and water instead. This gives you way more flexibility, since coal near water is much more frequent than coal, oil and water being close together.
CCLP Chevron Coal Liquefaction Process CCS Carbon capture and storage CO Carbon monoxide CO 2 Carbon dioxide CPI OPECConsumer Price Index CTL Coaltoliquids DCL Direct coal liquefaction DME Dimethyl ether DOD Department of Defense DOE Department of Energy EDS Exxon Donor Solvent ...
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